You are completely correct about AI detection software not being reliable (read more about that here), and I would also be very careful with the tell-tale signs that you think you see and that you interpret as AI – your gut is as unreliable as the detection softwares!*
I would start by considering what it is exactly that you hope to gain from confronting the student, and what you stand to lose by doing it.
It is possible that the student will admit to using AI in ways that you explicitly did not allow (but check your course policy first – is it really so clear that you can say that you are not allowing a specific use, like using AI to polish language or support editing?). When they admit to it, what happens then? Will you ask them to redo the work, or fail them on the task, or notify an oversight committee? And can you be 100% sure that they did not just admit to it to get out of an uncomfortable confrontation, and now they are carrying consequences for something they did not, in fact, do?
On the flip side of the coin, what happens if they do not admit to it? If they did not do it, you have now created a situation where they feel wrongly accused, probably wonder if you will always be looking out to catch them cheating even though they never did, so your relationship with that student has suffered. If other students hear about you wrongly accusing someone, that will also influence your relationship with them. And will you actually believe them if they say that they did not do it, or will you also be looking differently at them after this? It is of course also possible that your hunch is right, they did use AI, but they still don’t admit to it. Since you don’t have proof either way, where does it leave both of you now?
So in a nutshell, I think that you really don’t have anything to gain from confronting the student.
What you could, however, do, is address the topic more generally with the whole class. Not that you suspect someone is going against your policy, but going over your policy again, ask students what questions they have regarding that policy, if they know what that means in practice. Or, depending on what specifically looked like AI to you, addressing that you have seen a lot of this stye of writing, but that another style would be more appropriate; that you would appreciate if they edit their drafts in certain ways to avoid repetition; ...; meaning addressing specifically what it is that you want to be different in the texts they produce next time, rather than making it about whether AI wrote it or your students did.
*Three special cases that I can think of:
1) You detect plagiarism. That is academic misconduct and needs to be addressed as such, no matter whether it was the student themselves or AI and the student did not notice.
2) You find made-up references or clear misrepresentation of facts. You still don’t know completely for sure that they come from AI, but that does not matter. Those are obvious problems with the content of the essay, and you can address them as such, for example by asking the student to send you the (non-existent) article, or explain how they found the wrong “facts”.
3) The student forgot to edit the AI output to the extent that you find things like “Certainly! Here is the response to the essay question using scientific language”. In that case, you might just ask the student to explain why they added that sentence in the context.